Ortho-phenanthroline, C8H6N2, is a bidentate ligand, commonly abbreviated“phen”. Use a d-orbital diagram to explain why [Fe(phen)3]2+ is diamagnetic while [Fe(phen)2(H2O)2]2+ is paramagnetic
Ortho-phenanthroline, C8H6N2, is a bidentate ligand, commonly abbreviated“phen”. Use a d-orbital diagram to explain why [Fe(phen)3]2+...
The aquation of tris(1,10-phenanthroline)iron(II) in acid solution takes place according to the equation: Fe(phen)3 2+ + 3 H3O+ + 3 H2O → Fe(H2O)6 2+ + 3 phenH+. If the activation energy, Ea, is 126 kJ/mol and the rate constant at 30°C is 9.8 × 10-3 min-1, what is the frequency factor, A?
8. Explain why the complex (Fe(H2O) has de = 14,000 cm', while [Fe(H2O) has 3 = 9,350 cm. 9. Suggest a reason why copper'll) compounds are often colored but copper(l) compounds are colorless. 10. Sketch the d-orbital energy-level diagram for a square planar complex Spectrochemical series: COCN' >phen > NOx > en > NH3> NCS > H2O > F>RCOO > OH > CT > Br> 50m 750 nm 400 m Sem 430 nm 190 mm
The oxalate dianion or 'ox' (C2042) can act as a bidentate ligand. a) Explain what is meant by the term 'bidentate". B3. (1 mark) b) Reaction of FeClh.6H20 (1 mmol) with 'ox (3 mmol) in aqueous solution forms several octahedral complexes. Draw all possible isomers for the product of this reaction, indicating the charge on the complex ions (3 marks) c) Give the name for the type of stereoisomerism observed and hence assign and label each of the stereoisomers from...
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anyone please confirm my answers for 5&6? And can you explain
how to fill in the electrons for 7? Please and Thank you.
5. The values of A, for some coordination complexes are given below. (a) [Fe(ox)) --- 14,100 cm-1 (ox-oxalato ligand-----weak ligand] (b) [Fe(CN).-----35,000 cm ©) [Fe(CN)6]* -----33,800 cm (1) Explain reason(s) why A. of complex (a) and (b) are different (ii) Explain reason(s) why 4, of complex (b) and (c) are different 6. Answer the following questions...
2. Consider the O; molecule (a) Indicate the ground state orbital diagram, the ground state electron configuration, the bond order and whether O2 in the ground state is diamagnetic or paramagnetic. (8 points) (b) A Lewis structure obeying the octet rule can be drawn for O, as follows Does the above Lewis structure represent a paramagnetic state or a diamagnetic state? (2 points) (c)Use the molecular orbital diagram for O, to show that the above Lewis structure corresponds to an...
The complex ion [Co(H2O)6]3+is found to be diamagnetic whereas the complex ion [Fe(H2O)6]2+is found to be paramagnetic, with four unpaired electrons. Use the crystal field model to explain these observations.
Use molecular orbital theory to predict the following properties of the N2 2+ ion: (a) electron configuration; (b) bond order; (c) magnetic character (paramagnetic or diamagnetic); (d) whether the bond length is longer or shorter than in the N2 molecule; (e) whether the bond strength is greater or less than in the N2 molecule. Use the M.O. diagram for N2 in Figure 10.13 of Tro, Fridgen and Shaw as a starting point for this question.
1) Prepare the molecular orbital diagram for the OH- ion 2) Brief answers a) Explain why FeS is much less solute in water than Fe(OH)2 and Fe(OH)2 is much more soluble than Fe(OH)3 b)will Cr3+react more strongly with Cl-or PR3. Why? 3) a would you expect lead (Pb2+ soft to be found oxide in nature? b) Explain the following observation interns pf the HSAB theory: OH- + CH3HgS- --> CH3HgOH +S2- Equilibrium displaced to the left.
Prepare the full M.O. diagram for Ru(bpy)3 2+ including placing electrons on diagram, and explain why it is a diamagnetic complex.
ANSWER ALL QUESTIONS PLEASE 1. What are the characteristic electron configurations of transition metals? 2. What is the general trend in atomic size across a transition metal series? 3. Which electrons, 3d or 4s, have the lowest ionization energies in a transition metal? 4. What is the general trend of the reducing strength across a transition metal series? 5. Why do transition metals have similar chemical properties? 6. Name four transition metals that are essential to the biological system. 1. Write the...