Label the following complexes as Inert or Labile:
[Al(C2O4)3]3-
[V(H2O)6]3+
[V(H2O)6]2+
[Cr(C2O4)3]3-
[CoF6]3- (5P Ground State)
[Fe(CN)6]4-
[PtCl6]2-
Label the following complexes as Inert or Labile: [Al(C2O4)3]3- [V(H2O)6]3+ [V(H2O)6]2+ [Cr(C2O4)3]3- [CoF6]3- (5P Ground State) [Fe(CN)6]4-...
Which of the following octahedral complexes would be substitution inert? Which would be substitution labile ?(using the definition of H. Taube) (H2O)6Co+2, (NH3)6Co+3, (H2O)6Cr+2 , (H2O)6Cr+3, (H2O)6Ti+3, (H2O)6V+2, (H2O)6V+3, (CN)6Rh-3, Think of H2O, Cl- and Br- as weak field ligands, NH3 and CN- as strong field ligands. PLEASE SHOWYOUR WORK
Name the following coordination compounds using systematic nomenclature. 1. [Co(H2O)6]Cl2: 2. [Cr(NH3)6](NO3)3: 3. K4[Fe(CN)6]: 4. Na[Au(CN)4]: 5. [Co(H2O)2(en)2]Cl3: ANSWER 1-5 PLEASE!
Part A (2 marks) In the following pairs of complexes, which do you expect to have a larger ligand field splitting parameter Ao? Why? Explain? i) [Fe(NH3)612+ or [Fe(NH3). 13+ ii) (Co(CN)613- or [Rh(CN)613- Part B (3 maks) In the following pairs of complexes, which do you expect to be more labile? Why? Explain? ) [Cr(NH3)613+ or [Mn(NH3)6]3+ ii) (Co(CN)613- or [Rh(CN)613- ii) [Cr(NH3).]3+ or [V(NH3).]2+
Name the following compounds: 5. a) CuCla]2 b) Cr(H20)(NH3)]2 c) [Cr(H2O)4(NH)] SO4 d) K3[Fe(CN)6]
5. Name the following compounds: a) [CuCl4)? b) [Cr(H2O)(NH3)]*2 c) [Cr(H2O) (NH3)]SO4 d) K3 [Fe(CN)6]
4. Consider the following complexes. Na, [Fe(ox),] [Cr(H2O) (NHJ) SO, [Pt(en)(ONO)CI] Write the coordination sphere for the complexes I, II and III. [3 marks] in each of the Determine the oxidation state of the central atom coordination complex [3 marks] Determine the coordination number in each of the complexes. [3 marks) Name each of the complex using IUPAC system [6 marks) Draw the molecular geometry of complex II. [2 marks] Using Crystal Field Theory, draw the energy diagram of the...
Name the following complexes 11.Cr(OH2)3(OH)3 12.[Cr(NH3)6][Cr(CN)6] 13.TiCl3 14.Cp2Hf(CO)2 15.Fe(CO)5 16.Zr(C6H6)2 17.[Zn(OH2)4][ZnCl4] 18.TpMoO(OMe)2 19.Au(porphyin)(OH2)2 20.(CpW(CO)3)2 (contains a W–W bond)
For each of the following transition metal complexes, determine the oxidation state of the metal, its coordination number, and the number of d electrons on that metal. (a) RuO4 (b) (CO(NH3).]3+ (c) [Cr(H2O).]8+ (d) Cr(H2O)3Cl2 (e) [Fe(H2O).]3+ (1) (Co(NH3).]2+ (9) MOCI (h) (Pt(CN)4]2- () [Mn(H2O).]2+ (1) Re(CO).Br (k) (Ag(CN 2] (1) [ReH9]?
Name the following complexes: 1. K4[Fe(CN)6] 2. KMnO4 3. [CuBr4](NO3)2 4. [Co(en)2Cl2]Cl
calculuate valence electrons for each complex
(a) [Mn(H20)]3+ (d) [Fe(H20).]3+ (b) [Cr(H2O)6]2+ (e) [Co(NH3)4] * (h) [Pd(NH3).]4+ (c) [V(H2O).]2+ (1) [Ni(H2O)]2+ (1) [Re(CN).]3- (g) MoF6