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why is there no kd value when using the extraction of a carboxylic acid and 10%...

why is there no kd value when using the extraction of a carboxylic acid and 10% sodium bicarbonate? and why is there no kd value when using tbe extraction of an amine with HCl. both organic layers are combined with dichloromethane
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Answer #1

carboxylic acid forms sodium salt when treated with 10% sodium bicarbonate

amine being basic in nature forms alkyl ammoinium chloride salt

due to the salf formation there is kd value

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