TRUE/FALSE QUESTIONS
Question 1
Spontaneous processes proceed without outside intervention once
initiated. Yet, spontaneous processes are not always rapid.
Group of answer choices
True
False
Question 2
The sign of ∆G tells us how fast a reaction (or a process) might
occur.
Group of answer choices
True
False
Question 3
The sublimation of dry ice (solid CO2), where CO2(s) LaTeX:
\longrightarrow ⟶ CO2(g), has ∆S>0, ∆H>0, and ∆G<0 at
25°C.
Group of answer choices
True
False
Question 4
If a reaction is spontaneous based on favorable entropy change
(i.e., ∆S>0) at a given temperature, then the reverse of that
reaction should also be spontaneous (i.e. ∆S>0) at the same
temperature.
Group of answer choices
True
False
Question 5
During digestion, complex carbohydrates decompose into simple
sugars that our body can use and metabolize. As a result, the
carbohydrates experience a reduction in its entropy.
Group of answer choices
True
False
Question 6
Precipitation reactions tend to have ∆S°rxn < 0 due to the
formation of a solid precipitate from dissolved ions or molecules
in the solution.
Group of answer choices
True
False
Question 7
Consider the following hypothetical, reversible reaction: A+BLaTeX:
\longleftrightarrow ⟷C+D.
When ∆Grxn < 0 (negative) for this chemical reaction, then the reaction will proceed to the right toward products. When ∆Grxn > 0 (positive), however, the reaction will proceed to the left, toward reactants. Once the reaction reaches an equilibrium, ∆Grxn = 0.
Group of answer choices
True
False
Question 8
Exothermic reactions with a positive ∆S (i.e., ∆S>0) are
spontaneous only at low temperature (T).
Group of answer choices
True
False
Question 9
Endothermic reactions are never spontaneous at any temperature (T)
regardless the ∆S-value.
Group of answer choices
True
False
Question 10
At absolute zero temperature (i.e., 0.0 K), the entropy of a
perfect crystal is zero where molecules are highly ordered and
occupy the lowest vibrational, rotational and translational energy
microstates (i.e., W=1 in Boltzmann equation).
Group of answer choices
True
False
TRUE/FALSE QUESTIONS Question 1 Spontaneous processes proceed without outside intervention once initiated. Yet, spontaneous processes are...
Partial 0.44/0.5pts Question 1 Is each statement true or false? 1. false All spontaneous reactions occur quickly. 2. true The reverse of a spontaneous reaction is nonspontaneous. 3. false All spontaneous processes release heat. 4. true The boiling of water at 100°C and 1 atm is spontaneous. 5. false If a process increases the freedom of motion of the particles of a system, the entropy of the system decreases. 6. false The energy of the universe is constant; the entropy...
Question 3
2) A reaction that is spontaneous as written will proceed without outside intervention is also spontaneous in the reverse direction has an equilibrium position that lies far to the left is very slow 3) When a system is at equilibrium, A) the reverse process is spontaneous but the forward process is not B) the forward and the reverse processes are both spontaneous C) the forward process is spontaneous but the reverse process is not D) the process is...
2. Decide whether each of the following statements is true or false. If false, rewrite it to make it true. a. Entropy of the universe increases in all spontaneous reactions. wo False If entropy is bw enough it con be spontaneous, b. Reactions with a negative free energy change (A-Gº <0) are product-favored and occur with rapid transformation of reactants to products. True c. An exothermic reaction will always be spontaneous. I NO when AH is negative the reaction can...
1. True or False: a) A reaction is spontaneous if ΔSnn > 0. b) The Fourth Law of Thermodynamics states: The entropy of a pure, perfect crystal at O K is. c) For A(g) + B(g) D(g) + E(g), if ΔΗ'm < 0 and Δ5%n > 0, the reaction is spontaneous regardless of temperature. d) For A(g) + B(g) → D(g) + E(g), ifAH"m > 0 and Δ5%n < 0, it will be possible to find a temperature above which...
(1) The reaction the decomposition of ammonia is shown below. Calculate the total ∆H If bond energies in K/J: N≡N is 944, H-H is 436 and N-H is 388 Reactions: 2 NH3→N_2+3H_2 Explain reason for your answer (2) Which of the following statements is FALSE and why? A) Entropy is a state function. B) Endothermic processes decrease the entropy of surroundings, at constant T and P. C) Endothermic processes are never spontaneous. D) Entropy of the surroundings depends on the...
Q2: For a two-component solution, as x 2 → 1, which
of the following would apply to Component 1? Select all correct
answers.
Group of answer choices:
Raoult's Law
Henry's Law
Q3:
On the solid-gas co-existence curve on a phase diagram for a
molecule, which of the following statements are true? select all
answers that are correct. ("sub" subscript means "sublimation" in
the expressions below).
Group of answer choices
ΔsubS=0
ΔsubV=0
ΔsubH=0
Gsolid=Ggas
The temperature (T) is below the triple point...
nupiel 17 Problems 1. Answer the following questions in terms of thermodynamic principles. a. Consider the reaction represented below, which is spontaneous at 298 K. CO2(g) + 2 NH3(g) -> CO(NH2)2(s) + H2O(l); AH = -134 kJ i. For the reaction, indicate whether the standard entropy change, AS, is positive, or negative, or zero. Justify your answer. ii. Which factor, the change in enthalpy, AH, or the change in entropy, AS, provides the principal driving force for the reaction at...
Justify the following sentences by answering (T) for TRUE or (F) for FALSE. (1 mark each) AE is independent on the initial and final state of a system. The sum of entropy changes of the system and surroundings is always positive. The ratio of numerical values of partial pressures of the reaction participants is unitless. Q is small if products pressures are small, a large Q means a negative or good (favorable) contribution to the free energy For pure solids...
Match the term to the correct description. Choices may only be used once. Group of answer choices [ Choose ] An inhibitor molecule binds to the active site. Part of an enzyme where the substrate binds to Protein molecules that function as biological catalysts An inhibitor molecule binds to an allosteric site and prevents the substrate from binding to the active site. A substance...
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a 2 Mg(s) +,(@) 2 Mgo (s) AS b. CH206(s) → 2C,H,OH(I) + 2003(g) AS c. 2 NH3(g) + CO2(g) → H2O(l) + NH CONH3(aq) AS d. Cu(s) (at 100°C) → Cu(s) (at 25°C) AS 2. Which two variables can indicate if a reaction is spontaneous or not? 3. The second law of thermodynamics tells us that: a Energy is conserved. b. The entropy of...