1)
see experiment 1 and 2:
[NO] doubles
[H2] is constant
rate becomes 4 times
so, order of NO is 2
see experiment 2 and 3:
[NO] is constant
[H2] doubles
rate doubles
so, order of H2 is 1
overall order = 2 + 1 = 3
Rate law is:
rate = k*[NO]^2*[H2]
2)
Put values from 1st row of table in rate law
rate = k*[NO]^2*[H2]
2*10^-2 = k*0.00593^2*0.38^1
k = 1497 M-2.s-1
Answer: 1.50*10^3 M-2.s-1
|References For the reaction N2(8) 2 H,0(8) 2 NO(g) +2 H3 (g) at 1100° C, the following data have been obtained. NO...
B1. The following experimental data were obtained for the following reaction at 1000 K: 2 NO(g) + O2(g) 2 NO2(g) NOI (mol L OJ (mol L- Inital rate of reaction (mol L-'s - 0.0100 0.0200 0.0300 0.0200 0.0500 0.0200 3.02 x 10-5 3.02 x 10-4 2.72 x 10-4 (a) Determine the order of the reaction for each reactant (b) Determine the overall order of the reaction. Answer: (c) Calculate the rate constant at this temperature.
onlocatori entale References The reaction NO(g) +0,() + NO.(k)+(s) plays a role in the formation of titrogen dioxide in automobile engines Suppose a series of experiments measured the rate of this reaction at 500 K and produced the following data NO 101 rate - ANO]/A (01-L) (mol L-4) (mol-1,-1,) 0.00166 0.00415 5.51 x 10-17 0.00166 0.00830 1.10 x 10- 0.00498 0.00415 1.65 x 10-16 Derive a rate law for the reaction (Kate expressions take the general form: rate [ C...
For the reaction below, the following data were obtained at constant temperature. Reaction: A(g) + B(g) + C(g) D(g) Exp't Initial [A] (mol/L) Initial [B] (mol/L) Initial [C] (mol/L) Initial Rate (mol/Ls) 1 0.0100 0.1500 0.0200 1.24 10-2 2 0.0200 0.1500 0.0200 2.48 10-2 3 0.0200 0.3000 0.0200 9.90 10-2 4 0.0100 0.1500 0.0400 1.24 10-2 (a) What is the order with respect to each reactant? with respect to [A]. with respect to [B]. with respect to [C]. (b) Select...
Consider the reaction: 2 NO(g) + O2 (g)--> 2 NO2 (g)
The following data were obtained from three experiments using
the method of initial rates:
3. Consider the reaction: 2 NO(g) + O2(g) → 2 NO2(g) The following data were obtained from three experiments using the method of initial rates: Initial [NO] Initial rate NO Initial [02] mol mol L-1 mol L-1 L-15-1 0.010 0.010 Experiment 1 Experiment 2 Experiment 3 0.020 0.010 2.5 x 10-5 1.0 x 10-4 5.0...
4. Suppose the following data is obtained for the reaction: 2NO(g)+2H2(g) → N2(g)+2H20(g) [NO] [Hz] Rate (mol L 54) 0.1 0.1 1.4 x 10-4 0.2 0.1 5.6 x 10-4 0.1 0.2 2.8 x 10-4 Determine the rate law for the reaction
The reaction C 4 H 8 ( g ) ⟶ 2 C 2 H 4 ( g ) has an activation energy of 262 kJ / mol. At 600.0 K, the rate constant, k , is 6.1 × 10 − 8 s − 1 . What is the value of the rate constant at 835.0 K?
The reaction C 4 H 8 ( g ) ⟶ 2 C 2 H 4 ( g ) has an activation energy of 262 kJ / mol. At 600.0 K, the rate constant, k , is 6.1 × 10 − 8 s − 1 . What is the value of the rate constant at 795.0 K?
1. The kinetics of the following reaction have been studied: N2
+ 3 H2 → 2 NH3 The rate of of appearance of NH3 was measured as
∆[NH3]/∆t = 9.00 x 10-2 mol L-1 s-1
(a) What is the rate of the reaction in mol L-1 s-1?
(b) What is ∆[N2]/∆t in mol L-1 s-1?
(c) What is ∆[H2]/∆t in mol L-1 s-1?
2. The initial rate of the reaction of species A and B A + 2 B →...
Consider the following reaction. CH,(8) + 30,(8) 200,(g) + 2 H2O(g) Compound C, H.() 0,(g) CO2(g) H2O(g) AH; (kJ/mol) 52.4 0 -393.5 -241.8 What is the AH of the reaction? -687.7 kJ/mol -1323.0 kJ/mol -1218.2 kJ/mol 1323.0 kJ/mol
Problem #3 (20 marks) The following kinetic data (initial rates) were obtained for the reaction 2 ICI(g) + H2(g) → 12(g) + 2 HCI (9) Experiment [Cl]. (mmol/L) [Hz]. (mmol/L) V. (mol/L s) 3.0 3.0 14.8 X10-7 3.0 1.8 8.9 x10-7 1.5 1.8 4.44 x 10-7 3.7 1.3 ? (a) Write the rate law for the reaction (b) From the data, determine the value of the rate constant (c) Use the data to predict the reaction rate for experiment 4.