Question

1)

Give the product for the reaction of 1-butene with methanol in the presence of acid. The mechanism is the same as the mechanism for the addition of water to alkenes.

2-ethoxybutane

1-butanol

2-methoxybutane

1-ethoxybutane

1-methoxybutane

2)

What is the major product of the following reaction? HO I. CHOH IV. CH2OH IV. CH3 Ⅱ. OH CH3 HO CH O II

3)

Identify the best nucleophile in an SN2 reaction.

tert-butoxide ion

tert-pentoxide ion

isopropoxide ion

ethoxide ion

4)

Identify the alkyl halide that reacts the fastest in an SN1 reaction.

2-bromopropane

2-chloropropane

2-iodopropane

2-fluoropropane

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Answer #1

Alkene on reaction with alcohol forms carbocation, which on attack with nucleophile forms positive charge. Thus can be removed through deprotonation with alcohol CHO : ????? H2C CH3 CH3 1-butene CH3 ????? CH3 H3C :OCH3 2-methoxybutane

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