Draw a triacylglyceride made from glycerol and acetic acid.
3. Draw the triacylglyceride formed from glycerol and three molecules of oleic acid. 4. The melting point of stearic acid is 70°C, and the melting point of oleic acid is 4°C. Explain in detail why their melting points are so different. 5. Describe the primary, secondary and tertiary levels of structure of a protein. Which one(s) is affected by denaturation? 6. Draw the dipeptide formed from glycine and alanine. 114
1. Draw the structure of tripalmitin, the triacylglycerol made from glycerol and palmitic acid. CH2-OH CH-OH CH2-OH palmitic acid glycerol 2. Draw the structure of the product when linolenic acid has been completely halogenated with bromine (Bra). linolenic acid 3. Three fats, labeled X, Y, and Z, were analyzed for double bond content and found to have "iodine numbers" of 78, 147, and 180, respectively. Which of the fats was the most saturated?
Draw a triacylglycerol (triglyceride) made from glycerol, myristic acid (CH, (CH),COOH , palmitic acid (CH,(CH),COOH), and oleic acid (CH,(CH),CH=CH(CH,),COOH (cis)] . Place palmitic acid at the middle position. Cis/trans isometry is graded; it may help to draw hydrogen atoms associated with the carbon atoms of the double bond. Select Draw Draw Rings More Erase Predict whether this triacylglycerol is a liquid or a solid at room temperature (25 °C). liquid O solid
Draw a triacylglycerol (triglyceride) made from glycerol, myristic acid (CH,(CH),COOH) , palmitic acid [CH,(CH) 14COOH) , and oleic acid (CH,(CH),CH=CH(CH),COOH(cis)] . Place palmitic acid at the middle position. Cis/trans isometry is graded; it may help to draw hydrogen atoms associated with the carbon atoms of the double bond. Select Draw Rings More Erase Q2Q Predict whether this triacylglycerol is a liquid or a solid at room temperature (25 °C). O solid liquid
For a buffer made from sodium acetate and acetic acid, the Ka of acetic acid is 1.8E-5. What mass of sodium acetate (NaCH3CO2) must be added to 2.50 L of 0.68 M acetic acid to make a buffer solution with pH = 5.75? The answer should be in two significant figures.
Draw a structural formula for the amide that forms from acetic acid and piperidine.
An aqueous solution is made with the salt obtained from combining the weak acid acetic acid, CH3CO2H, and the weak base methylamine, CH2NH2. Is the solution acidic, basic, or neutral? Ka=1.8×10−5 and Kb=4.4×10−4
Draw a flow chart for complete oxidation of glycerol. How many ATP molecules can be made from 1 molecule of table sugar?
BONUS Question: (4 pts) Acrolein (propenal) is made commercially from glycerol by heating in the presence of sulfuric acid. Propose a stepwise mechanism to explain this reaction. OH HO O H H2SO4 heat glycerol acrolein
For acetic acid pKa =4.74. A buffer solution was made using 0.30 mole of acetic acid and an unspecified and amount of sodium acetatein water to make 2.00 liters of solution. The solution pH was 4.91. Calculate the number of moles of sodium acetate used.