An example of a reaction where ∆G = 0 is
all acid-base reactions
H2O(g)→H2O(l) @STP
any reaction that is over
H2O(g)→ H2O(s) @STP
Which reaction below is spontaneous at SATP?
∆Hº=34.1 kJ and ∆Sº=46.2 J/K
∆Hº=71.7 kJ and ∆Sº=-4.25 J/K
∆Hº=-11.1 kJ and ∆Sº=-61.8 J/K
∆Hº=9.95 kJ and ∆Sº=57.4 J/K
Answer : ∆Hº = 9.95 kJ and ∆Sº = 57.4 J/K
Explanation :
∆Gº = ∆Hº - T ∆Sº
= 9.95 - 273 x 0.0574
= - 5.7 kJ
here ∆Gº < 0 . so this condition is spontaneous.
in remaining all cases , ∆Gº is > 0 .
An example of a reaction where ∆G = 0 is all acid-base reactions H2O(g)→H2O(l)...
An example of a reaction where ∆G = 0 is H2O(s)→H2O(l) @SATP any reaction that is over H2O(g)→H2O(l) @SATP all combustion reactions
1a) For which of the following reactions is ΔSo > 0? a. 2 C2H6(g) + 7 O2(g) à 4 CO2(g) + 6 H2O(g) b. H2CO(g) + O2(g) à CO2(g) + H2O(l) c. N2(g) + 3 H2(g) à 2 NH3(g) d. NH3(g) + HI(g) à NH4I(s) 1b) For a particular chemical reaction ΔH = 7.0 kJ and ΔS = –17 J/K. Under what temperature condition is the reaction spontaneous? a) When T > 412 K. b) The reaction is not spontaneous...
An example of a reaction where ∆G = 0 is a. any double displacement reaction b. CO2(s)→CO2(g) @SATP c. CO2(s)→CO2(l) @SATP d. any reaction that is done
Calculate the standard change in Gibbs free energy of the
following reactions at Standard Ambient Temperature and Pressure
(SATP where T = 25°C and P = 1 atm) and label them as spontaneous
or nonspontaneous.
(a) 2 SO2(g) + O2(g) 2 SO3(g): ΔΗ.-197.8 k , dS.-188.0 J/K kJ, and the reaction is Selectv (b) 2 C6H6(/) + 15 O2(g) 12 CO2(g) + 6 H2O(/); ΔΗ.-6535.0 kJ, S.-439.2 J/K kJ, and the reaction is Select (c) C(diamond); C(graphite); ΔΗ--19 ki, as...
2. For the following example, identify the following.
H2O(l) → H2O(s)
question 2 options
a negative ΔH and a negative ΔS
a positive ΔH and a negative ΔS
a negative ΔH and a positive ΔS
a positive ΔH and a positive ΔS
It is not possible to determine without more information.
3. Calculate ΔS°rxn for the following reaction. The S° for each
species is shown below the reaction.
C2H2(g) + H2(g) →
C2H4(g)
S°(J/mol∙K) 200.9 130.7 219.3
Question 4 options:...
Given the following Thermodynamic data: CO2(g) H2O(l) NH3(g) CO(NH2)2(s) DeltaHof (kJ/mol): -393.5 -285.85 -45.9 -333.2 So (J/K.mol): 214 70 193 105 (a) Calculate DeltaHo, DeltaSo, and DeltaGo at 25oC for the following reaction: CO2(g) + 2NH3(g) = CO(NH2)2(s) + H2O(l) (b) What is DeltaGo at 250oC? (Assume DeltaHo and DeltaSo do not change with temperature.) (c) Is the reaction spontaneous at each temperature? (Answer: (a) DeltaHo = -133.8 kJ; DeltaSo = -425 J/K; DeltaGo = -7.15 kJ; (b) DeltaGo =...
Classify each of the following reactions as one of these four types: • spontaneous at all temperatures • not spontaneous at any temperature • spontaneous below a certain temperature but not above • spontaneous above a certain temperature but not below See Table 17.1 in Tro, Fridgen and Shaw. (a) 2 NO2 (g) → 2 NO (g) + O2 (g); ∆H = 115.4 kJ; ∆S = 146.5 J/K (b) MgS (s) + Pb (s) → PbS (s) + Mg (s);...
AH = -116.4 kJ/mol 4. Consider the following reaction: NH4NO3 (s) N20 (g) + 2 H2O (g) Calculate AGº for the reaction. Substance Sº (J/mol K) NH4NO3 (s) 151 N20 (g) 220 H2O (g) 183
Classify each of the following reactions as one of these four types: • spontaneous at all temperatures • not spontaneous at any temperature • spontaneous below a certain temperature but not above • spontaneous above a certain temperature but not below See Table 17.1 in Tro, Fridgen and Shaw. (a) PbS (s) + Mg (s) → Mg (s) + Pb (s); ∆H = 66 kJ; ∆S = -9 J/K (b) 2 SO2 (g) + O2 (g) → 2 SO3 (g);...
For the reaction: C(s) + H2O(g) CO(g) + H2(g), ΔH° = 131 kJ and ΔS° = 128 J/K at 298 K. At temperatures greater than ______ K, this reaction is spontaneous under standard conditions. a. 1.02 K b. 273 K c. 1023 K d. 753 K