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Image for Incase you can't read the text.... The flavor and odor of fruits comes primarily from the esters they contain.

Incase you can't read the text.... The flavor and odor of fruits comes primarily from the esters they contain. For example, a major component in the flavor of oranges is octyl acetate. Draw the organic products formed when octyl acetate reacts with aqueous sodium hydroxide.

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Concepts and reason

This problem is based on the concept of hydrolysis of esters.

An ester is hydrolyzed to a carboxylic acid and an alcohol when treated with aqueous acid or aqueous base. Under alkaline conditions, the carboxylic acid is obtained in the form as its salt.

Fundamentals

Alkaline hydrolysis of ester is done with strong base NaOH
and acts as nucleophilic reagent. This reaction is reversible, since carboxylate anion has tendency to react with an alcohol and gives back ester.

Attack of on carbonyl take place as follows resulting formation of tetrahedral intermediate:

NaOH)
om
Ö^

Hydrolysis of product formed from step 1 followed by reaction with NaOH
is as follows:

+ ОЙ
го
o
+
НО,

Ans:

The products of the reaction are:

o
+ OH

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