If the E°' for the NAD/NADH half cell is -0.32V and for the fumarate/succinate half cell is 0.031V, calculate the ΔG°' for the reaction NADH + H+ + fumarate → NAD+ + succinate given F = 96.5 kJ/Vmol.
| -12.55 kJ/mol | ||
| -67.74 kJ/mol | ||
| 67.74 kJ/mol | ||
| -55.78 kJ/mol | ||
| 55.78 kJ/mol |
E=-0.32+0.031 V
=0.289V
∆Go
’ = –nF ∆Eo
∆Go
’ = –2(96.5 kJ V–1 mol –1)(0.289V) = – 55.77kJ /mol
Therefore answer is -55.78kj/mol
If the E°' for the NAD/NADH half cell is -0.32V and for the fumarate/succinate half cell...
What would ΔG∘′ be for an enzyme that oxidizes succinate with NAD+ instead of FAD? Oxidant Reductant n E∘′(V) NAD++H++2e− ⇌ NADH 2 −0.32 Fumarate+2H++2e− ⇌ Succinate 2 0.03 Use the following equation and F = 96.485 kJ/mol. ΔG°’ = ‒nFΔE°’ Express your answer to two significant figures and include the appropriate units. ΔG∘'=
What would ΔG∘′ be for an enzyme that oxidizes succinate with NAD+ instead of FAD? Oxidant Reductant n E∘′(V) NAD++H++2e− ⇌ NADH 2 −0.32 Fumarate+2H++2e− ⇌ Succinate 2 0.03 Use the following equation and F = 96.485 kJ/mol. ΔG°’ = ‒nFΔE°’ Express your answer to two significant figures and include the appropriate units ΔG′= value w/ units please
E Volts) 6 co2/glucose 0.43] -0.5 I-0.42] -0.4 NAD /NADH 0.32] -03 -0.2 -0.1 Fumarate/succinate 0.03] 0.0 [0.10] +0.1 2 H /H2 I- 0.27] FADIFADH2 0.18] S°/H2S CoQ/CoQH2 +0.2 Cyt C (Fe )Cyt C (Fe+) [0.25] +0.3- +0.4 +0.5 +0.6 No,INO2 [0.421 Fe3+/Fe2+ 4 0,H20 (0.82108 10.77) +07
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