Natural gas is mostly methane, but it also contains some ethane and propane. The enthalpies of combustion of methane, ethane and propane are -810, -1420, and -2030 kJ mol-1, respectively.
(A) Complete the chemical reactions for the combustion of these fuels and calculate the amount of heat released per mole of oxygen and carbon dioxide produced for the three gases using the enthalpy of the reaction.
i. For methane: CH4 + O2 -> ___________
Heat released per mole of O2 consumed = ____________ kJ
Heat released per mole of CO2 = ____________ kJ
ii. For ethane: C2H6 + O2 -> ____________
Heat released per mole of O2 consumed = __________ kJ
Heat released per mole of CO2= __________ kJ
iii. For propane: C3H8 + O2 -> _____________
Heat released per mole of O2 consumed = ___________ kJ
Heat released per mole of CO2 = ___________kJ
B) Using the enthalpy values above, determine the energy generated per gram of fuel.
Heat released per gram of methane = ________
Heat released per gram of ethane = ________
Heat released per gram of propane = ________
Natural gas is mostly methane, but it also contains some ethane and propane. The enthalpies of...
A gaseous fuel mixture contains 25.3% methane (CH4), 38.2% ethane (C2H6), and the rest propane (C3H8) by volume. When the fuel mixture contained in a 1.76 L tank, stored at 756 mmHg and 298 K, undergoes complete combustion, how much heat is emitted? (Assume that the water produced by the combustion is in the gaseous state.) Express your answer with the appropriate units.
Problem: Bapco needs to burn natural-gas fuel that contains 75 mol% methane, 15 mol% ethane, and 10 mol% nitrogen. The following two reactions takes place: CH4(g) 20209) CO2(0) 2H2o) C2H6 (g) + 3.502(g) 2C02(g)3H20 (g) a) What is the standard heat of combustion (kJ/mol) of the fuel at 25 oC with water(g) as a product b) The fuel is supplied to a furnace with 60% excess air, both entering at 250C. The products leave at 600°C. If the combustion is...
A natural gas fuel consists of the following volumetric composition: Methane, CH4: 92.5 % Ethane, C2H6: 3.7 % Propane, C3H8: 0.8 % Nitrogen, N2: 3 % (a) Write out the complete combustion equations for all the combustible constituents individually. (b) Calculate the stoichiometric air to fuel (A/F) ratio on a volume basis. (c) Determine the wet volumetric analysis of the combustion products. (d) Find the dry volumetric analysis of the combustion products.
Using the standard molar heat of combustion of hydrogen, methane, and ethane (given below), find the enthalpy change for 2CH4(g) → C2H6(g) + H2(g) H2 + ½ O2 → H2O ΔHo = -285.8 kJ CH4 + 2O2 → CO2 + 2H2O ΔHo = -890.4 kJ C2H6 + (7/2)O2 → 2CO2 + 3H2O ΔHo = -1559.9 kJ
Be sure to answer all parts.A sample of natural gas contains 6.327 moles of methane (CH4), 0.803 moles of ethane (C2H6), and 0.216 moles of propane (C3H8). If the total pressure of the gases is 2.99 atm, what are the partial pressures of the gases?
Natural gas is typically about 95% methane. The other 5% is a complex mixture of other hydrocarbons (percent by mass). Let’s assume the 5% is all ethane, C2H6. Balance and calculate the heat of combustion of ethane, ∆Hcomb (kJ/mole), using reaction below. C2H6 (g) + O2 (g) → CO2 (g) + H2O (g)
a) A natural gas fuel contains 80 v/o methane, 10 v/o ethane, and 10 v/o propane. Determine the heat released by combustion of 1m3 of the gas. Assume that products of combustion are CO2 and liquid H2O. b) How would the answer to part (a) change if the water produced were vaporized?
A gaseous fuel mixture stored at 745 mmHg and 298 K contains only methane (CH4) and propane (C3H8). When 11.3 L of this fuel mixture is burned, it produces 760 kJ of heat. What is the mole fraction of methane in the mixture? (Assume that the water produced by the combustion is in the gaseous state.)
1.f) Methane gas (CH4) enters a combustion chamber at a rate of 3 kg/sec at a temperature of 25 °C. A 200% theoretical air is supplied at a temperature of 400K. At the middle of methane combustion process (i.e., after 50% of methane gas is burnt), liquid propane (C3H8) at 25°C is injected at a rate that produces neither CO nor O2 in the flue gases. Assume steady state and adiabatic process at 1 atm, calculate the following i. The...
2. Natural gas containing a mixture of methane, ethane, propane, and butane is burned in a furnace with excess air. One hundred kmol/h of a gas containing 94.4 mole% methane, 3.40% ethane, 0.60% propane, and 0.50% butane is to be burned with 17% excess air. a) Calculate the molar flow rate of the air. b) Now instead of using numerical values, we will work the problem by deriving an equation. Define the following variables: i.molar flow of the fuel gas:...