A heat engine uses 100. mg of helium gas and follows the cycle shown in the figure.
a) Determine the pressure, volume, and temperature of the gas at points 1, 2, and 3.
b) Determine the engine’s efficiency.
c) What would be the maximum efficiency of the engine to be able to operate between the maximum and minimum temperatures?

In isothermal process temperature T remains constant.
The ideal gas law is given as follows:
Here, p is pressure, V is volume, n is number of moles R is gas constant, and T is temperature.
The relation between number n of moles to mass m is given as follows:
Here, M is molar mass.
Convert the units of mass m of helium from mg to grams as follows:
Substitute
for M, and 0.1g for m in the above equation to obtain the number of moles n of helium.
(a)
Use figure, pressure
, volume
, and temperature
at point 1 are given as follows:
Convert the units of
from atm to pascal as follows:
The volume
at point 1 is given as follows:
Convert the units of
from cubic centimetre to cubic metre as follows:
Use ideal gas law obtain the following relation:
Here,
is temperature at point1.
Substitute 100kPa for
,
for
, 0.025mol for n, and
in the above equation to obtain the value of
.
(b)
Use figure, pressure
, volume
, and temperature
at point 2 are given as follows:
Convert the units of
from atm to pascal as follows:
The volume
at point 2 is given as follows:
Convert the units of
from cubic centimetre to cubic metre as follows:
Here,
is temperature at point1.
Substitute 500kPa for
,
for
, 0.025mol for n, and
in the above equation to obtain the value of
.
Use figure, pressure
, volume
, and temperature
at point 3 are given as follows:
Convert the units of
from atm to pascal as follows:
Since in isothermal process temperature remains constant, the temperature at point 2 must be equal to temperature at point 3.
Use ideal gas law, for constant temperature the relation between pressure p and volume V is given as follows:
Rearrange the above equation for
as follows:
Substitute 500kPa for
, 100kPa for
, and
for
in the above equation to obtain the value of
as follows:
(b)
The efficiency of the engine
is given as follows:
Here, W is work done by engine and Q is heat given to the engine.
Obtain the work done W by the engine as follows:
The heat energy given to the system Q is given as follows:
The efficiency of the engine is given as follows:
Thus, the efficiency of the engine is
.
The efficiency of the engine
is given as follows:
Here,
is minimum temperature, and
is maximum temperature.
Substitute 600K for
, 3000K for
, in the above equation to obtain the efficiency of the engine as follows:
Thus, the efficiency of the engine between maximum and minimum temperature is
.